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《能源学会志》2020,93(2):624-633
In order to solve the problem of marine microplastics and realize the harmless resource utilization of plastics, the gasification experiments of polycarbonate (PC) microplastics were carried out in supercritical water and a novel seawater gasification of microplastic experiment was investigated. In this paper, the effects of different operating conditions (temperature, time, feedstock concentration, pressure) on gasification performance were discussed. The gasification kinetic of microplastics in supercritical water was calculated. The experimental results showed that the increase in gasification temperature and time enhanced the cracking reaction and free radical reaction of the microplastics to increase the gasification efficiency, while the reduction in feedstock concentration improved the gasification efficiency by increasing the gasification level of unit feedstock. The change in pressure had no significant effect on gasification due to the fact that the properties of the supercritical water were not significantly changed. It was found that the valuable results that all alkali metal salts in seawater promote hydrogen conversion, while in terms of carbon conversion, only KCl, CaCl2, NaHCO3 and seawater had a significant catalytic effect on the gasification. Seawater gasification of microplastics was a potential resource utilization method. Finally, it was considered that the PC plastic gasification conformed to the random nucleation and subsequent growth model (n = 3), and the reaction activation energy was 230.45 kJ/mol, which was smaller than that of traditional pyrolysis. 相似文献
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《Journal of the European Ceramic Society》2022,42(1):162-168
Excellent electrical properties and the improved long-term stability of ZnO varistor ceramics were simultaneously achieved by doping NiO. The microstructural features were investigated using X-ray diffractometer, scanning electron microscopy, and energy dispersive spectroscopy, while the intrinsic point defects were characterized using frequency domain dielectric spectroscopy and verified by photoluminescence and Raman spectra. The results indicated that in the ZnO varistor ceramics, a reverse manipulation of donor point defects, i.e., suppressing mobile zinc interstitial but increasing stable oxygen vacancy, was achieved. The long-term stability of NiO-doped ZnO ceramics was improved via a decrease in zinc interstitial density, with a degradation rate of 0.064 μA cm?2 h?0.5. Meanwhile, due to an increase in oxygen vacancy density, the excellent nonlinear current–voltage performance, i.e., a high nonlinear coefficient (72.9), low leakage current density (0.08 μA cm?2), and low grain resistivity (13.43 × 10?3 Ω m), was maintained. The findings of this study provide a possible method for developing high-performance ZnO varistor ceramics by manipulating point defects. 相似文献
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Generation scheduling is an important concern of the current power system which is suffering from many obstacles of limited generation resources, grown energy demand and fuel price, inconsistent load demand and fluctuations of available wind power in case of the thermal–wind system. Smart grid system has a great potential of tumbling existing power system difficulties with intelligent infrastructure and computation technologies. Three different distributed energy resources, namely, distributed generation, demand response and gridable vehicles are used in this paper to overcome the power system hitches. The classical generation scheduling is solved with insertion of the cost of demand response and the cost model pertaining to underestimation and overestimation of fluctuating wind power. The modified optimization problem is solved using an efficient Global best artificial bee colony algorithm for 10 generating units test system. Generation scheduling in the smart grid environment yields a significant reduction in the total cost. 相似文献
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The incorporation of Distributed Generation (DG) under the Virtual Power Plant (VPP) concept allows the market integration of several and largely dispersed electric power sources. One matter of concern for the VPP owner and operator is to follow the hourly schedule regardless of the stochastic nature of some of its sources or any unpredicted generation outages. This study presents a Decision Tree (DT) based methodology that prepares for the dispatching of power equivalent to the possible loss of the highest injection of one of the sources of the VPP (according to day-ahead hourly schedule) to the rest of its sources, on an hour-ahead horizon. This allows VPP operators to provide firm capacity and participate effectively in the energy market. 相似文献
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《Journal of the European Ceramic Society》2017,37(3):1013-1022
A glass-based composite coating incorporating YSZ particles was prepared by sintering on K438G superalloy substrates. The YSZ additions increased the cyclic oxidation resistance at 1000 °C, while the formation of zircon resulting from interfacial reactions between YSZ and the glass matrix worked reversely. Besides, the YSZ inclusions changed the crystallization behavior of the glass matrix, and only anorthite precipitated during cyclic oxidation. Due to the synergy of sand-blasting and sealing effect of the glass-based coating, the oxidation behavior of K438G was changed and a layer of alumina instead of chromia formed at the substrate/coating interface. Furthermore, a gahnite layer formed at the alumina/gahnite interface because of interfacial reactions between alumina and the glass matrix, leading to the formation of a bi-layered thermally grown oxide. Thus, the alumina layer was protected from the attack of the active glass matrix. Accordingly, the coated K438G superalloy exhibited satisfactory oxidation resistance at 1000 °C. 相似文献
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